The census records of 2001 show Chapui to have a population of 5185. Males amount to 55% of the population; females make up 45% while children less than 6 years of age constitute 12% of the population. The average literacy rate of 59% is lower than the national average of 59.5%. The male literacy is 71% and the female literacy is 46%. The area is famous as a coal mining area.
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